Wang, A., Li, J. & Zhang, T. Heterogeneous single-atom catalysis. Nat. Rev. Chem. 2, 65–81 (2018).
Li, X. et al. Functional CeOx nanoglues for robust atomically dispersed catalysts. Nature 611, 284–288 (2022).
Yang, J. et al. Dynamic behavior of single-atom catalysts in electrocatalysis: identification of Cu–N3 as an active site for the oxygen reduction reaction. J. Am. Chem. Soc. 143, 14530–14539 (2021).
Liu, L., Chen, T. & Chen, Z. Understanding the dynamic aggregation in single‐atom catalysis. Adv. Sci. 11, 2308046 (2024).
Hu, J. et al. Sulfur vacancy-rich MoS2 as a catalyst for the hydrogenation of CO2 to methanol. Nat. Catal. 4, 242–250 (2021).
Zheng, J. et al. High loading of transition metal single atoms on chalcogenide catalysts. J. Am. Chem. Soc. 143, 7979–7990 (2021).
Gan, X. et al. 2H/1T phase transition of multilayer MoS2 by electrochemical incorporation of S vacancies. ACS A.E.M. 1, 4754–4765 (2018).
Hou, H. L. et al. High-yield preparation of exfoliated 1T-MoS2 with SERS activity. Chem. Mater. 31, 5725–5734 (2019).
Ophus, C. Four-dimensional scanning transmission electron microscopy (4D-STEM): From scanning nanodiffraction to ptychography and beyond. Microsc. Microanal. 25, 563–582 (2019).
Chen, Z. et al. Electron ptychography achieves atomic-resolution limits set by lattice vibrations. Science 372, 826–831 (2021).
Liu, G. et al. MoS2 monolayer catalyst doped with isolated Co atoms for the hydrodeoxygenation reaction. Nat. Chem. 9, 810–816 (2017).
Li, H. et al. Atomic structure and dynamics of single platinum atom interactions with monolayer MoS2. ACS Nano 11, 3392–3403 (2017).
Qu, W. et al. Single-atom catalysts reveal the dinuclear characteristic of active sites in NO selective reduction with NH3. Nat. Commun. 11, 1532 (2020).
Shi, Z. et al. Phase-dependent growth of Pt on MoS2 for highly efficient H2 evolution. Nature 621, 300–305 (2023).
Xiong, Y. et al. Chemically switchable n-type and p-type conduction in bismuth selenide nanoribbons for thermoelectric energy harvesting. ACS nano 15, 2791–2799 (2021).
Fu, F. et al. Z-contrast and electron energy loss spectroscopy study of passive layer formation at ferroelectric PbTiO3/Pt interfaces. Appl. Phys. Lett. 87, 262904 (2005).
Ahn, C. C. & Krivanek, O. L. EELS Atlas: A Reference Collection of Electron Energy Loss Spectra Covering All Stable Elements (Gatan, Warrendale, PA, 1983).
Chen, Z. X. et al. Addressing the quantitative conversion bottleneck in single-atom catalysis. Nat. Commun. 13, 2807 (2022).
Yan, Q. Q. et al. Reversing the charge transfer between platinum and sulfur-doped carbon support for electrocatalytic hydrogen evolution. Nat. Commun. 10, 4977 (2019).
Huang, F. Low-temperature acetylene semi-hydrogenation over the Pd1–Cu1 dual-atom catalyst. J. Am. Chem. Soc. 144, 18485–18493 (2022).
Kan, M. et al. Structures and phase transition of a MoS2 monolayer. J. Phys. Chem. C 118, 1515–1522 (2014).
Li, W. H. et al. Creating high regioselectivity by electronic metal–support interaction of a single-atomic-site catalyst. J. Am. Chem. Soc. 143, 15453–15461 (2021).
Song, J. et al. Promoting dinuclear‐type catalysis in Cu1–C3N4 single‐atom catalysts. Adv. Mater. 34, 2204638 (2022).
Zhang, X. et al. Platinum–copper single atom alloy catalysts with high performance towards glycerol hydrogenolysis. Nat. Commun. 10, 5812 (2019).
Wang, Z. Y. et al. Pt single-atom electrocatalysts at Cu2O nanowires for boosting electrochemical sensing toward glucose. Chem. Eng. J. 495, 153564 (2024).
Shi, R. et al. Room-temperature electrochemical acetylene reduction to ethylene with high conversion and selectivity. Nat. Catal. 4, 565–574 (2021).
Li, H. et al. σ-Alkynyl adsorption enables electrocatalytic semihydrogenation of terminal alkynes with easy-reducible/passivated groups over amorphous PdSx nanocapsules. J. Am. Chem. Soc. 144, 19456–19465 (2022).
Gu, J. et al. Synergizing metal–support interactions and spatial confinement boosts dynamics of atomic nickel for hydrogenations. Nat. Nanotechnol. 16, 1141–1149 (2021).
Gao, J. et al. Mixed metal-organic framework with multiple binding sites for efficient C2H2/CO2 separation. Angew. Chem. Int. Ed. 11, 4396–4400 (2020).
Wondergem, C. S., Hartman, T. & Weckhuysen, B. M. In situ shell-isolated nanoparticle-enhanced Raman spectroscopy to unravel sequential hydrogenation of phenylacetylene over platinum nanoparticles. ACS Catal. 9, 10794–10802 (2019).
Pei, G. X. et al. Performance of Cu-alloyed Pd single-atom catalyst for semihydrogenation of acetylene under simulated front-end conditions. ACS Catal. 7, 1491–1500 (2017).
Gao, Q. et al. Atomic layers of B2CuPd on Cu nanocubes as catalysts for selective hydrogenation. J. Am. Chem. Soc. 145, 19961–19968 (2023).
Li, B. et al. Introduction of π-complexation into porous aromatic framework for highly selective adsorption of ethylene over ethane. J. Am. Chem. Soc. 136, 8654–8660 (2014).
Tsai, C. et al. Electrochemical generation of sulfur vacancies in the basal plane of MoS2 for hydrogen evolution. Nat. Commun. 8, 15113 (2017).